Available online
Description
Stereochemical changes resulting from intramolecular re-arrangement of inorganic complexes.
Stereochemical changes resulting from intramolecular re-arrangement of inorganic complexes.
| Module code and title: | S304, The nature of chemistry |
|---|---|
| Item code: | S304; 16 |
| First transmission date: | 1978 |
| Published: | 1978 |
| Rights Statement: | |
| Restrictions on use: | |
| Duration: | 00:24:00 |
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| Producer: | Barrie Whatley |
| Contributor: | Charles Harding |
| Publisher: | BBC Open University |
| Keyword(s): | Animated film; Biological systems; Carbon; Hydrogen; Inorganic complexes; Inorganic compounds; Intramolecular re-arrangements; Models; Nuclear magnetic resonance spectroscopy |
| Footage description: | Footage - Molecular model (0'18"-0'30") - Molecular model of phosphorous pentafluoride (1'29"-2'00") - Fluorine 19 NMR spectrum of phosphorous pentafluoride (2'01"-2'14") - Graphic of ammonia. Infra-red spectrum of ammonia. Molecular model of ammonia (2'39"-4'07") - Energy curve barrier of ammonia (4'20"-4'57") - Graphic of methylaziridine (5'48"-6'00") - Trigonal bipyramidal molecular model (6'55"-7'24") - Graphic of dimethylamino PF4. Molecular model of dimethylamino PF4 (7'49"-8'18") - Phosphorous-31 spectrum at lowering temperatures (9'02"-9'32") - Molecular model of dimethylamino PF4. Series of NMR spectra (9'45"-10'59") - Animation of fluorine exchange. Molecular model of dimethylamino PF4. Animation of Berry twist (11'00"-13'14") - Graphic of dithiocarbomato group. Model of octohedral compound. Series of NMR spectra (14'56"-16'43") - Animation of rearrangement of methyl groups. Models of enantiomers (17'10"-19'23"). Square planar & tetrahedral models (19'31"-19'37") - Diagram of nickel complex. NMR spectra of nickel complex at different temperatures. Square planar & tetrahedral models (19'53"-21'36") - Animation of square planar complex interconverting (21'56"-22'50"). |
| Master spool number: | 6HT/72143 |
| Production number: | 00525_1206 |
| Videofinder number: | 902 |
| Available to public: | no |
