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Description
This programme deals with the high oxidation states found in the first transition series and illustrates what a 3d orbital is and shows the way it can be represented.
Metadata describing this Open University video programme
| Module code and title: |
S343, Inorganic chemistry |
| Item code: |
S343; VCR1A Pt2; Band 2 & 3 |
| Recording date: |
1988-08-09 |
| Published: |
1988 |
| Rights Statement: |
Rights owned or controlled by The Open University |
| Restrictions on use: |
This material can be used in accordance with The Open University conditions of use. A link to the conditions can be found at the bottom of all OUDA web pages. |
| Duration: |
01:00:00 |
| + Show more... |
| Track listing: |
track listing for this programme
|
Track 1
|
Chemistry of Titanium |
|
Track 2
|
Chemistry of Maganese |
|
Track 3
|
Chemistry of Cobalt |
|
Track 4
|
Transition Series Oxidation States |
|
Track 5
|
High Oxidation States in the first transition series |
|
Track 6
|
The Oxidation States of Vanadium |
|
Track 7
|
Orbitals 3i |
|
Track 8
|
Tetrahedral symmetries 3ii |
|
Track 9
|
Octahedral symmetries 3iii |
|
| Producer: |
Michael Peet |
| Contributor: |
Jan Bright |
| Publisher: |
BBC Open University |
| Keyword(s): |
Angular function; Chromium; Ions; Iron; Periodic table; Principal quantum number; Reduction; Schroedinger's equation; Total wave function; Vanadium |
| Footage description: |
Footage - Titanium dioxide. Tetrachloride. (0'01"-1'17") - Sulphuric acid added to titanium dioxide and boiled, zinc added (1'20"-2'48") - Manganese dissolving in solution. Potassium persulphate and silver nitrate added (2'52"-3'57" ) - Manganese II sulphate dissolved in sulphuric acid. Sodium bismuthate added .Solution filtered leaving a purple liquid (3'58"-4'45") - Sodium hydroxide added to solution of manganese II. Oxygen bubbled through. Hydrogen peroxide added converting it to manganese dioxide (5'16"-6'21") - Manganese dioxide being heated with potassium hydroxide and potassium nitrate, turning to solid on cooling. Solid dissolved in water. Acid added giving manganate VII. Green alkaline reduced with sodium sulphite giving manganate V (6'22"-8'00"). Manganese oxidation states from +2 to +7 (8'01"-9'38") - Cobalt metal dissolved in perchloric acid (9'43"-10'07") - Electrolysis of acid solution of aqueous cobalt 2 (10'08"-11'05") - Warming of aqueous tripositive ion (11'06"-11'25") - Sodium hydroxide added to aqueous dipositive ion. Stream of oxygen to speed up reaction. Hydroxide compound of cobalt 3 (11'26"-12'06") - Graphic of acid and alkali formulae (12'07"-13'22") - Ammonium chloride dissolved in aqueous diposotive ion. Ammonia solution added to give hexammine complex of cobalt 2. Oxidation to give hexammine complex of cobalt 3. Crystal of hexammine cobalt 3 chloride (13'23"-15'07") - Jars of chromiun 2+, manganese 2, iron 2, cobalt 2 and nickel 2 (15'32"-17'01") - Oxidation of chromium 2 (17'02"-17'55") - Oxidation of iron 2 (18'11"-18'31") - Cobalt oxidized by electrolysis (19'34"-20'00"). Review of materials and products (20'07"-22'25") - Oxidation of iron 2 by electrolysis (22'26"-23'16") - Chromate 6 in alkali and acid. Chromium 3 (23'23"-25'43") - Chart of oxidation states of potassium to manganese (25'44"-27'03") - Oxidation of iron. Chart of oxidation states of potassium to zinc (27'04"-29'30") - Copper dichloride heated in fluorine giving copper in oxidation state 3. Process repeated with nickel 2 (29'31"-32'08") - Oxidation states of vanadium. Vanadium 5 (32'13"-34'22"). |
| Master spool number: |
HOU6330 |
| Production number: |
HOU6199 |
| Videofinder number: |
2768 |
| Available to public: |
no |
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